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Entropically driven self-assembly and interaction in suspension

by: , Yodh
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 359, No. 1782. (15 May 2001), pp. 921-937.


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In this paper we present fundamental studies elucidating the role of entropy in particle suspensions. We focus on systems composed of large colloidal particles along with a second, usually smaller species such as a particle or polymer. We describe direct measurements of these interactions in suspension, and we systematically show how these forces can be used to control the self-assembly of colloidal particles. The paper provides a unified review of the experiments from our laboratory, and in a few cases touches on very recent results.


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